Oxidatively-induced aromatic cyanation mediated by Ni(iii).
نویسندگان
چکیده
A Ni(ii) complex with two t-butylisocyanide ligands supported by a N3C(-) type tetradentate ligand was synthesized and characterized. Quantitative generation of the aromatic cyanation product, (tBu)N3C-CN, is observed by reacting this Ni(ii) complex with 1 equiv. of an oxidant. Reactivity studies suggest that this oxidatively-induced cyanation involves a heterolytic cleavage of the N-(t)Bu bond and is mediated by Ni(iii).
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ورودعنوان ژورنال:
- Dalton transactions
دوره 45 21 شماره
صفحات -
تاریخ انتشار 2016